Structure Database (LMSD)

Common Name
mLPA(O-18:0)
Systematic Name
1-O-octadecyl-sn-glycero-3-phosphoric acid methyl ester
Synonyms
LM ID
LMGP00000065
Formula
Exact Mass
Calculate m/z
438.311028
Status
Active

Classification

References

Taxonomy Information

Curated from
NCBI taxonomy class
Reference
Homo sapiens (#9606)
Mammalia (#40674)
A novel self-lipid antigen targets human T cells against CD1c(+) leukemias.,
J Exp Med, 2014
Pubmed ID: 24935257

String Representations

InChiKey (Click to copy)
FIBCZHAELLGUEG-JOCHJYFZSA-N
InChi (Click to copy)
InChI=1S/C22H47O6P/c1-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-27-20-22(23)21-28-29(24,25)26-2/h22-23H,3-21H2,1-2H3,(H,24,25)/t22-/m1/s1
SMILES (Click to copy)
[C@](COP(=O)(O)OC)([H])(O)COCCCCCCCCCCCCCCCCCC

Other Databases

CHEBI ID
PubChem CID

Calculated Physicochemical Properties

Heavy Atoms 29
Rings 0
Aromatic Rings 0
Rotatable Bonds 23
Van der Waals Molecular Volume 461.73
Topological Polar Surface Area 85.22
Hydrogen Bond Donors 2
Hydrogen Bond Acceptors 6
logP 7.70
Molar Refractivity 121.00

Admin

Created at
-
Updated at
25th Apr 2022
LIPID MAPS® abbreviations for glycerophospholipids (GP)

The LIPID MAPS® glycerophospholipid abbreviations (PC, PE, etc.) are used here to refer to species with one or two radyl side-chains where the structures of the side chains are indicated within parentheses in the 'Headgroup(sn1/sn2)' format (e.g. PC(16:0/18:1(9Z)). By default, R stereochemistry at the C-2 carbon of glycerol and attachment of the headgroup at the sn3 position is assumed. Also, acyl chains are assumed by default. The 'O-' prefix is used to indicate the presence of an alkyl ether substituent e.g. PC(O-16:0/18:1(9Z)), whereas the 'P-' prefix is used for the 1Z-alkenyl ether (Plasmalogen) substituent e.g. PC(P-16:0/18:1(9Z)).

For molecules with opposite (S) stereochemistry at C2 of the glycerol group and attachment of the headgroup at the sn1 position, the stereochemistry specification of [S] is appended to the abbreviation. The 'Headgroup(sn3/sn2)' abbreviation format is used.

For molecules with unknown stereochemistry at the C-2 carbon of the glycerol group, the stereochemistry specification of [U] is appended to the abbreviation and the structure is drawn with C-2 stereochemistry unspecified.